@prefix skos: <http://www.w3.org/2004/02/skos/core#> .
@prefix uneskos: <http://purl.org/umu/uneskos#> .
@prefix isothes: <http://purl.org/iso25964/skos-thes#> .

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  skos:hiddenLabel "Induction asymétrique"@fr, "Asymmetric induction"@en ;
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  skos:prefLabel "induction asymétrique"@fr, "asymmetric induction"@en ;
  skos:definition "In stereochemistry, asymmetric induction (also enantioinduction) describes the preferential formation in a chemical reaction of one enantiomer or diastereoisomer over the other as a result of the influence of a chiral feature present in the substrate, reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis. Asymmetric induction was introduced by Hermann Emil Fischer based on his work on carbohydrates. Several types of induction exist. Internal asymmetric induction makes use of a chiral center bound to the reactive center through a covalent bond and remains so during the reaction. The starting material is often derived from chiral pool synthesis. In relayed asymmetric induction the chiral information is introduced in a separate step and removed again in a separate chemical reaction. Special synthons are called chiral auxiliaries. In external asymmetric induction chiral information is introduced in the transition state through a catalyst of chiral ligand. This method of asymmetric synthesis is economically most desirable. (From Wikipedia)"@en .

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